Comment: EXACTLY!

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You are in a good position to seek out private alternatives to helping folks in need...and gently persuade those that are apt to listen. I have a friend that started a private Charity called Realities for Children and it is totally funded by voluntary donations...surely there are some private charities near you that you could volunteer at and ..who knows...maybe you can end up getting paid by a private charity.
I would not give up my job (unless I absolutely hated it and the people i work with) simply due to it being contra to a libertarian concept...hell....anyone that uses dollars is participating in a gangster run system. Take your money and use it to live the life of the non aggression principle and good things will flow your way.