I use XFCE Ubuntu or Xubuntu because I like the classic menu-driven desktop environment that lacks the Amazon search stuff found in Unity and is also lighter weight in terms of RAM usage.
I was a big fan of Gnome 2, but switched to XFCE when Gnome 3 came out.
I also prefer how Ubuntu renders fonts in comparison to Fedora or Debian. I have interest in Arch Linux, but have stuck with Xubuntu for now because of it's ease of installation.
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